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Bilirubin is a byproduct of the destruction of red blood cells in the spleen. Bilirubin is processed by the liver into a water soluble form that is then expelled through the bile duct into the intestines where it passes in waste.

Hyperbilirubinemia, or jaundice, is the result of a buildup of bilirubin in the bloodstream. It is usually a sign of a serious illness in adults, but is normal in newborn infants. Newborns often re-absorb bilirubin through the intestine until their diet improves, raising the bilirubin levels in the body. However, on occasion, this can lead to kernicterus, a potentially life threatening condition.

Bilirubin breaks down under light and in cases of infantile jaundice infants are often put under bright lights to reduce their bilirubin levels.

Bilirubin at Wikipedia

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